Abstract

Polymeric nanocomposites are among the most exciting and promising classes of materials discovered recently. A number of physical properties are successfully enhanced when a polymer is modified with small amount of nanoclay on condition that the clay is dispersed at nanoscopic level. In this research, comparative rheological tests on binders and mechanical tests on asphalt mixtures containing unmodified and nanoclay modified bitumen, were carried out. Two types of nanoclay were used: Nanofill-15 and Cloisite-15A. Rheological tests on binder were penetration, softening point, ductility, and aging effect. Mechanical tests on asphalt mixture were Marshall stability, indirect tensile strength, resilient modulus, diametric fatigue, and dynamic creep tests. Test results show that nanoclay can improve properties such as stability, resilient modulus, and indirect tensile strength and result in superior performance compared to that of unmodified bitumen under dynamic creep. Nanoclays do not seem to have beneficial effect on fatigue behavior in low temperature. Optimum binder content and void in total mixture increase by adding nanoclay to bitumen.

References

1.
Pinnavaia
,
T. J.
and
Beall
,
G. W.
,
Polymer–Clay Nanocomposites
,
John Wiley and Sons Ltd.
,
London
,
2000
.
2.
Grim
,
R. E.
, “
Physicao-Chemical Properties of Soils: Clay Minerals
,”
J. Soil Mech. and Found. Div.
 0044-7994, Vol.
85
,
1959
, pp.
1
17
.
3.
Lan
,
T.
,
Kaviratna
,
P. D.
, and
Pinnavaia
,
T. J.
, “
Mechanism of Clay Factoid Exfoliation in Epoxy–Clay Nanocomposites
,”
Chem. Mater.
 0897-4756, Vol.
7
,
1995
, pp.
2144
2150
. https://doi.org/10.1021/cm00059a023
4.
Theng
,
B. K. G.
,
Formation and Properties of Clay-Polymer Complexes
,
Elsevier
,
Amsterdam
,
1979
.
5.
Southern Clay Products Inc. Website, http://www.nanoclay.com/faqs.asp (Last accessed Oct. 25
2004
).
6.
Nguyen
,
Q. T.
and
Baird
,
D. G.
,
2007
, “
Process for Increasing the Exfoliation and Dispersion of Nanoclay Particles into Polymer Matrices Using Supercritical Carbon Dioxide
,” Ph.D. thesis,
Virginia Polytechnic Institute and State University
, Blacksburg, VA.
7.
Manias
E.
, ‘‘
Origins of the Materials Properties Enhancements in Polymer/Clay Nanocomposites, Focus on Poly-propylene/Montmorillonite Hybrids
,’’
Nanocomposites 2001, Delivering New Value to Plastics
,
Golovoy
A.
, Ed.,
ECM Publications
,
Il
,
2001
, Vol.
1
.
8.
Chen
,
J.-S.
,
Liao
,
M.-C.
, and
Tsai
,
H.-H.
, “
Evaluation and Optimization of the Engineering Properties of Polymer-Modified
,”
J. Fail Anal Prev.
, Vol.
2
, No.
3
,
2002
, pp.
75
83
.
9.
Radziszewski
,
P.
, “
Modified Asphalt Mixtures Resistance to Permanent Deformations
,”
J. Civ Eng. Manage.
, Vol.
13
,
2007
, pp.
307
315
.
10.
Lan
,
T.
and
Pinnavaia
,
T. J.
, “
Clay-Reinforced Epoxy Nanocomposites
,”
Chem. Mater.
 0897-4756, Vol.
6
,
1994
, pp.
2216
2219
. https://doi.org/10.1021/cm00048a006
11.
Kornmann
,
X.
,
Lindberg
,
H.
, and
Berglund
,
L. A.
, “
Synthesis of Epoxy–Clay Nanocomposites: Influence of the Nature of the Clay on STructure
,”
Polymer
 0032-3861, Vol.
42
,
2001
, pp.
1303
1310
. https://doi.org/10.1016/S0032-3861(00)00346-3
12.
Zerda
,
A. S.
and
Lesser
,
A. J.
, “
Intercalated Clay Nanocomposites: Morphology, Mechanics and Fracture Behavior
,”
J. Polym. Sci., Part B: Polym. Phys.
 0887-6266, Vol.
39
,
2001
, pp.
1137
1146
. https://doi.org/10.1002/polb.1090
13.
Becker
,
O.
,
Varley
,
R.
, and
Simon
,
G. P.
, “
Morphology, Thermal Relaxations and Mechanical Properties of Layered Silicate Nanocomposites Based upon High-Functionality Epoxy Resins
,”
Polymer
 0032-3861, Vol.
43
,
2002
, pp.
4365
4373
. https://doi.org/10.1016/S0032-3861(02)00269-0
14.
Liu
,
Y. L.
,
Hsu
,
C. Y.
,
Wei
,
W. L.
, and
Jeng
,
R. J.
, “
Preparation and Thermal Properties of Epoxy–Silica Nanocomposites from Nanoscale Colloidal Silica
,”
Polymer
 0032-3861, Vol.
44
,
2003
, pp.
5159
5167
. https://doi.org/10.1016/S0032-3861(03)00519-6
15.
Ghile
,
D. B.
,
Effects of Nanoclay Modification on Rheology of Bitumen and on Performance of Asphalt Mixtures
,
Delft University of Technology
,
Delft
,
2005
.
16.
Chow
,
W. S.
,
Development Of Thermoplastic Nanocomposites Based On Blends of Polyamide and Polypropylene
,
Material and Mineral Resources Engineering, University Sains Malaysia
,
Penang
,
2003
.
17.
Yasmin
,
A.
,
Luo
,
J. J.
,
Abot
,
J. L.
, and
Daniel
,
I. M.
, “
Mechanical and Thermal Behavior of Clay/Epoxy Nanocomposites
,”
Compos. Sci. Technol.
 0266-3538, Vol.
66
, No.
14
,
2006
, pp.
2415
2422
. https://doi.org/10.1016/j.compscitech.2006.03.011
18.
ASTM D1559–89,
1994
, “
Standard Test Method for Resistance to Plastic Flow of Bituminous Mixtures Using Marshall Apparatus
,” Annual Book of ASTM Standards, ASTM International, West Conshohocken.
19.
ASTM D4123–82,
1995
, “
Standard Test Method for Indirect Tension Test for Resilient Modulus of Bituminous Mixtures
,” Annual Book of ASTM Standards, Vol.
04.03
, ASTM International, West Conshohocken, PA, pp.
1
4
.
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