Abstract

This paper presents the results of a study on mechanical properties and microstructure in a SS316 wrapper irradiated in a 40MWt/13MWe fast breeder test reactor at Kalpakkam, India. Transmission electron microscopy (TEM) examination and mechanical property evaluation were carried out on the hexagonal wrapper subjected to different displacement damages up to a maximum of 83 dpa at an operating temperature of about 673 K. The steel irradiated to 83 dpa showed an increase in the yield strength and ultimate tensile strength, with a reduction in uniform elongation to about 8 %–10 % from about 20 % in the unirradiated material. Density measurements on the specimen from different portions of the irradiated wrapper showed a peak volumetric swelling of about 3.5 % at a damage of 83 dpa. TEM studies showed extensive void formation at 40 dpa and beyond in addition to extensive precipitation and formation of dislocation loops. The void density and size showed a progressive increase with displacement damage. The precipitates were identified to be of nickel and silicon enriched M6C type of η phase, while radiation induced G phase was also observed at 83 dpa. The increase in strength and reduction in ductility with increase in dpa is attributed to irradiation hardening, which is supported by the increase in defect density as observed from the dislocation substructure and increase in the void density and size. The paper would discuss the degradation in mechanical property in terms of the microstructural changes.

References

1.
Mannan
,
S. L.
,
Chetal
,
S. C.
,
Baldev
R.
, and
Bhoje
,
S. B.
, “
Selection of Materials for Prototype Fast Breeder Reactor
,”
Proceedings of Seminar on Materials R & D for PFBR
,
S. L.
Mannan
and
M. D.
Matthew
, Eds.,
IGCAR
,
Kalpakkam, India
,
2003
, pp.
9
43
.
2.
Lallement
,
R.
,
Maikailoff
,
H.
,
Mustellier
,
J. P.
, and
Villeneuve
,
J.
, “
Fast breeder reactor fuel design principles and performance
,”
Nucl. Energy
 0140-4067, Vol.
28
,
1989
, pp.
41
49
.
3.
Bailly
,
H.
,
Menessier
,
D.
, and
Prunier
,
C.
,
The Nuclear Fuel of Pressurized Water Reactors and Fast Neutron Reactors
,
Lavoisier Publishing
,
Paris
,
1999
, pp.
16
36
.
4.
Garner
,
F. A.
, “
Irradiation Performance of Cladding and Structural Steels in Liquid Metal Reactors
,”
Nuclear Materials, Part 1, Materials Science and Technology—A Comprehensive Treatment
, Vol.
10
,
B. R. T.
Frost
, Ed.,
VCH Publishers
,
New York
,
1994
, pp.
419
543
.
5.
Yang
,
W. J. S.
, “
Precipitate Evolution in Type 316 SS Irradiated in EBR-II
,”
Radiation Induced Changes in Microstructure, 13th International Symposium, ASTM STP955
,
F. A.
Garner
,
N. H.
Packan
, and
A. S.
Kumar
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1987
, pp.
628
646
.
6.
Mannan
,
S. L.
and
Sivaprasad
,
P. V.
,
Encyclopedia of Materials Science and Engineering
,
J.
Buschow
,
R. W.
Cahn
,
M. C.
Flemings
,
B.
Ilschner
,
E. J.
Kramer
, and
S.
Mahajan
, Eds.,
Elsevier
,
New York
,
2001
, pp.
2857
2865
.
7.
Puigh
,
R. J.
and
Garner
,
F. A.
, “
Neutron-Induced Swelling in Cold-Worked Titanium-Modified AISI 316 Alloys
,”
Radiation Induced Changes in Microstructure, 13th International Symposium, ASTM STP955
,
F. A.
Garner
,
N. H.
Packan
, and
A. S.
Kumar
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1987
, pp.
154
160
.
8.
Venkiteswaran
,
C. N.
,
Parameswaran
,
P.
,
Anandaraj
,
V.
,
Karthik
,
V.
,
Muralidharan
,
N. G.
,
Venugopal
,
V.
,
Saroja
,
S.
,
Vijayalakshmi
,
M.
,
Kasiviswanathan
,
K. V.
, and
Baldev
,
R.
, “
TEM Studies on Irradiated Wrapper of FBTR at Different Displacement Damages
,”
Advances in Stainless Steels
,
University Press
,
India
,
2009
(in press).
9.
Lucas
,
G. E.
, “
The development of small specimen mechanical test techniques
,”
J. Nucl. Mater.
 0022-3115, Vol.
117
,
1983
, pp.
327
329
. https://doi.org/10.1016/0022-3115(83)90041-7
10.
Lucas
,
G. E.
,
Odette
,
G. R.
, and
Sheckherd
,
J. W.
, “
The Use of Small-Scale Specimens for Testing Irradiated Materials
,”
ASTM STP888
,
W. R.
Corwin
and
G. E.
Lucas
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1986
, pp.
112
140
.
11.
Karthik
,
V.
,
Laha
,
K.
,
Kasiviswanathan
,
K. V.
, and
Baldev
,
R.
, “
Determination of Mechanical Property Gradients in Heat-Affected Zones of Ferritic Steel Weldments by Shear-Punch Tests
,”
Small Specimen Test Techniques: Fourth Volume, ASTM STP1418
,
M. A.
Sokolov
,
J. D.
Landes
, and
G. E.
Lucas
, Eds.,
ASTM International
,
West Conshohocken, PA
,
2002
pp.
380
405
.
12.
Williams
,
D.
and
Carter
,
B.
,
Transmission Electron Microscopy—A Textbook for Materials Science
,
Plenum Press
,
New York
,
1996
.
13.
Hankin
,
G. L.
,
Hamilton
,
M. B.
,
Toloczko
M. L.
,
Garner
F. A.
, and
Faulkner
R. G.
, “
Shear punch testing on 59Ni isotopically-doped model austenitic alloys after irradiation in FFTF at different He/dpa ratios
,”
J. Nucl. Mater.
 0022-3115, Vols.
258
–263,
1998
, pp.
1657
1663
. https://doi.org/10.1016/S0022-3115(98)00204-9
14.
Klueh
,
R. L.
, and
Grassbeck
,
M. L.
, “
Tensile Properties and Swelling of 20 % Coldworked Type 316 Stainless Steel Irradiated in a High Flux Isotope Reactor (HFIR)
,”
12th International Symposium in Effects of Radiation on Materials, ASTM STP870
,
F. A.
Garner
and
J. S.
Perrin
, Eds.,
1985
, pp.
768
782
.
15.
Pedraza
,
D. F.
and
Maziasz
,
P. J.
, “
Void—Precipitate Association During Neutron Irradiation of Stainless Steel
,”
13th International Symposium (Part I), Radiation Induced Changes in Microstructure: ASTM STP955
,
F. A.
Garner
,
N. H.
Packan
, and
A. S.
Kumar
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1987
, pp.
161
194
.
16.
Maziasz
,
P. J.
, “
Some effects of increased helium content on boid formation and solute segregation in neutron irradiated type 316 stainless steel
,”
J. Nucl. Mater.
 0022-3115, Vols.
108–109
,
1982
, pp.
359
384
. https://doi.org/10.1016/0022-3115(82)90505-0
17.
Lee
,
E. H.
,
Maziasz
,
P. J.
, and
Rowcliffe
,
A. F.
, “
The Structure and Composition of Phases Occurring in Austenitic Stainless Steels in Thermal and Irradiation Environments
,”
Conference Proceedings of Phase Stability During Irradiation
,
J. R.
Holland
,
L. K.
Mansur
, and
D. I.
Potter
, Eds.,
The Metallurgical Society of AIME
,
Warrendale, PA
,
1981
, pp.
257
270
.
18.
Ukai
,
S.
,
Akasaka
,
N.
,
Hattori
,
K.
, and
Onose
,
S.
, “
The Effects of Phase Stability on Void Swelling in P, Ti Modified 316 Stainless Steels During Neutron Irradiation
,”
Effects of Radiation on Materials: 18th International Symposium, ASTM STP1325
,
R. K.
Nanstad
,
M. L.
Hamilton
,
F. A.
Garner
, and
A. S.
Kumar
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1999
, pp.
808
821
.
19.
Maziasz
,
P. J.
and
Odette
,
G. R.
Wide Area Beam Averaged AEM of Precipitate Particles Extracted on Replicas from Type 316 Stainless Steel
,”
Proceedings of the 41st Annual EMSA Meeting
,
G. W.
Bailey
, Ed.,
San Francisco Press, Inc.
,
San Francisco, CA
,
1983
, pp.
198
199
.
20.
Williams
,
T. M.
, “
Stainless Steels 84
,”
International Conference Held at Chalmers University, Sweden
,
The Institute of Metals London
,
London, UK
,
1985
, pp.
403
412
.
21.
Da Casa
,
C.
,
Nileshwar
,
V. B.
, and
Melford
,
D. A.
, “
M23C6 precipitation in unstabilized stainless steel
,”
J. Iron Steel Inst., London
 0021-1567, Vol.
207
,
1969
, pp.
1325
1332
.
22.
Lam
,
N. Q.
and
Okamoto
,
P. R.
, “
Solute segregation and precipitation under heavy-ion bombardment
,”
J. Nucl. Mater.
 0022-3115, Vol.
78
,
1978
, pp.
408
418
. https://doi.org/10.1016/0022-3115(78)90462-2
23.
Johnson
,
W. G.
,
Morris
,
W. G.
, and
Turkalo
,
A. M.
, “
Radiation Effects in Breeder Reactor Structural Materials
,”
Metallurgical Society
,
AIME
,
New York
,
1977
, pp.
421
430
.
24.
Hamilton
,
M. L.
,
Yang
,
W. J. S.
, and
Garner
,
F. A.
, “
Mechanical Properties and Fracture Behaviour of 20 % Cold-Worked 316 Stainless Steel Irradiated to Very High Neutron Exposures
,”
Influence of Radiation in Material Properties: 13th International Symposium (Part II), ASTM STP956
,
F. A.
Garner
,
C. H.
Henager
, Jr.
, and
N.
Igata
, Eds.,
ASTM International
,
West Conshohocken, PA
,
1987
, pp.
245
270
.
25.
Garner
,
F. A.
and
Wolfer
,
W. G.
, “
Factors which determine the swelling behavior of austentic stainless steels
,”
J. Nucl. Mater.
 0022-3115, Vol.
122
,
1984
, pp.
201
206
. https://doi.org/10.1016/0022-3115(84)90596-8
26.
Esmailzadeh
,
B.
,
Kumar
,
A. S.
, and
Garner
,
F. A.
, “
The influence of silicon on void nucleation in irradiated alloys
,”
J. Nucl. Mater.
 0022-3115, Vols.
133–134
,
1985
, pp.
590
593
. https://doi.org/10.1016/0022-3115(85)90216-8
This content is only available via PDF.
You do not currently have access to this content.