Abstract

Glyphosate herbicide labels generally recommend addition of ammonium sulfate (AMS) to the spray solution, which often improves weed control, especially when mixed with hard water. AMS in solution disassociates, and the sulfate binds with cations in the spray solution, preventing the development of glyphosate-cation complexes that tend to have lower absorption into plant leaves. In addition, the ammonium ion can associate with the glyphosate molecule, which helps facilitate glyphosate absorption into the leaf. The recommended AMS rate is 1–2 % w/w, and AMS is available in both dry and liquid formulations. Applicators generally find AMS inconvenient to use because of the high use rate and handling issues. Several companies are marketing low-rate water conditioner products to be used as an alternative to AMS with glyphosate. Pesticide applicators like the convenience of low-rate water conditioners, but performance of these products has been inconsistent. Field experiments were conducted near Manhattan, KS, from 2005 to 2008 to compare the efficacy of glyphosate with AMS and various commercial water conditioners on velvetleaf, sorghum, corn, and sunflower. Each experiment consisted of a sublethal (0.31 or 0.43 kg ae/ha) dose of glyphosate applied in combination with the recommended application rate of each adjuvant. Water hardness, environmental conditions, and plant growth stages varied by experiment. Control of all assay species with glyphosate was enhanced by the addition of AMS, unless control was near complete in the absence of AMS. Commercial water conditioner products that included an AMS component at the equivalent rate of 1 % w/w gave equal or slightly better control than glyphosate plus 1 % w/w AMS. Commercial water conditioners that did not provide an equivalent amount of AMS gave less control than glyphosate with 1 % or 2 % w/w AMS and were often no better than glyphosate alone for the low-rate products.

References

1.
Duke
,
S. O.
, and
Powles
,
S. B.
, “
Glyphosate: A Once in a Century Herbicide
,”
Pest Manage. Sci.
 1526-498X, Vol.
64
,
2008
, pp.
319
325
. https://doi.org/10.1002/ps.1518
2.
Peterson
,
D.
,
Olson
,
B.
,
Al-Khatib
,
K.
,
Currie
,
R.
,
Dille
,
J. A.
,
Falk
,
J.
,
Geier
,
P.
,
Regehr
,
D.
,
Stahlman
,
P.
, and
Thompson
,
C.
, “
Glyphosate Stewardship: Optimizing and Preserving Glyphosate Performance
,” Kansas State University Extension Publication,
2007
, MF-2767.
3.
Bernards
,
M. L.
,
Thelen
,
K. D.
, and
Penner
,
D.
, “
Glyphosate Efficacy is Antagonized by Manganese
,”
Weed Technol.
 0890-037X, Vol.
19
,
2005
, pp.
27
34
. https://doi.org/10.1614/WT-03-193R2
4.
Hall
,
G. J.
,
Hart
,
C. A.
, and
Jones
,
C. A.
, “
Plants as Sources of Cations Antagonistic to Glyphosate Activity
,”
Pest Manage. Sci.
 1526-498X, Vol.
56
,
2000
, pp.
351
358
. https://doi.org/10.1002/(SICI)1526-4998(200004)56:4<351::AID-PS151>3.0.CO;2-A
5.
Nalewaja
,
J. D.
, and
Matysiak
,
R.
, “
Influence of Diammonium Sulfate and Other Salts on Glyphosate Phytotoxicity
,”
Pestic. Sci.
 0031-613X, Vol.
38
,
1993
, pp.
77
84
. https://doi.org/10.1002/ps.2780380203
6.
O’Sullivan
,
P. A.
,
O’Donovan
,
J. T.
, and
Hamman
,
W. M.
, “
Influence of Non-Ionic Surfactants, Ammonium Sulfate, Water Quality and Spray Volume on the Phytotoxicity of Glyphosate
,”
Can. J. Plant Sci.
 0008-4220, Vol.
61
,
1981
, pp.
391
400
.
7.
Stahlman
,
P. W.
, and
Phillips
,
W. M.
, “
Effects of Water Quality and Spray Volume on Glyphosate Phytotoxicity
,”
Weed Sci.
 0043-1745, Vol.
27
,
1979
, pp.
38
41
.
8.
Thelen
,
K. D.
,
Jackson
,
E. P.
, and
Penner
,
D.
, “
The Basis for the Hard Water Antagonism of Glyphosate Activity
,”
Weed Sci.
 0043-1745, Vol.
43
,
1995
, pp.
541
548
.
9.
Nalewaja
,
J. D.
,
Matysiak
,
R.
, and
Freeman
,
T. P.
, “
Spray Droplet Residual of Glyphosate in Various Carriers
,”
Weed Sci.
 0043-1745, Vol.
40
,
1992
, pp.
576
589
.
10.
Pratt
,
D.
,
Kells
,
J. J.
, and
Penner
,
D.
, “
Substitutes for Ammonium Sulfate as Additives with Glyphosate and Glufosinate
,”
Weed Technol.
 0890-037X, Vol.
17
,
2003
, pp.
576
581
. https://doi.org/10.1614/0890-037X(2003)017[0576:SFASAA]2.0.CO;2
11.
Ramsdale
,
F. K.
,
Messersmith
,
C. G.
, and
Nalewaja
,
J. D.
, “
Spray Volume, Formulation, Ammonium Sulfate, and Nozzle Effects on Glyphosate Efficacy
,”
Weed Technol.
 0890-037X, Vol.
17
,
2003
, pp.
589
598
. https://doi.org/10.1614/WT02-157
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