Thermal Conductivity Equations Based on Brownian Motion in Suspensions of Nanoparticles (Nanofluids)

Thermal conductivity equations for the suspension of nanoparticles (nanofluids) have been derived from the kinetic theory of particles under relaxation time approximations. These equations, which take into account the microconvection caused by the particle Brownian motion, can be used to evaluate the contribution of particle Brownian motion to thermal transport in nanofluids. The relaxation time of the particle Brownian motion is found to be significantly affected by the long-time tail in Brownian motion, which indicates a surprising persistence of particle velocity. The long-time tail in Brownian motion could play a significant role in the enhanced thermal conductivity in nanofluids, as suggested by the comparison between the theoretical results and the experimental data for the $Al2O3$-in-water nanofluids.